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Why Ozone Cracking Happens in Rubber Products and How to Prevent It
2024/09/30 30

Scenario

Ozone cracking is one of the leading causes of premature rubber failure in outdoor, automotive, electrical, and industrial applications. Rubber seals, gaskets, and molded components may initially perform well but gradually develop fine surface cracks after prolonged exposure to ozone. These cracks reduce elasticity, weaken sealing performance, and eventually lead to leakage, equipment downtime, and increased maintenance costs.

Breakdown

Ozone attacks the double bonds within certain rubber polymers, especially when components are under continuous tension or compression. Materials such as Natural Rubber (NR) and SBR are highly susceptible, while EPDM, Silicone, and FKM provide outstanding ozone resistance. Environmental factors including ultraviolet (UV) exposure, temperature fluctuations, humidity, and mechanical stress can further accelerate cracking. Choosing rubber based only on cost or oil resistance often results in premature failure when products are used outdoors or in ozone-rich environments.

Generally, the ozone resistance of common rubber materials ranks as follows:

EPDM ≈ Silicone ≈ FKM (Excellent) > NBR (Moderate) > SBR > Natural Rubber (Poor).

Selecting the appropriate elastomer according to the actual working environment is critical for maximizing service life.

Solution

Preventing ozone cracking requires a complete engineering solution rather than simply replacing the rubber material. Manufacturers should first evaluate the application's ozone concentration, outdoor exposure, operating temperature, deformation, and expected service life before selecting the most suitable compound. Optimized formulations, precision mold design, and strict production control further improve long-term durability.

As an industry example, Ningbo Yongbo Rubber & Plastic Products Co., Ltd. specializes in customized rubber and plastic components for industrial applications. By recommending ozone-resistant materials such as EPDM, Silicone, or FKM based on customer requirements and combining custom mold development with consistent manufacturing processes, the company helps customers reduce ozone-related failures, improve sealing reliability, and extend product service life in demanding environments.

Warning

Ozone damage is often overlooked because early cracks are extremely small and may not affect performance immediately. However, once rubber remains under continuous stress, these cracks can spread rapidly and lead to leakage or complete component failure. Always evaluate environmental exposure, material compatibility, and long-term aging performance before mass production. Choosing the right rubber compound from the beginning is the most effective way to reduce maintenance costs and improve product reliability.

Prev:How to Choose Rubber That Can Survive High Temperatures Next:Prevent Rubber Seal Failure: Understanding Compression Set Performance
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